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Hollywood sexiest couple Brad Pitt and Angelina Jolie were ready for their fifth child, Brad Pitt announced at the Venice Film Festival where he was promoting his new film “The Assassination of Jesse James by the Coward Robert Ford” on September 2, 2007.

Pitt and Jolie already have four children, three adopted from Cambodia, Ethiopia and Vietnam, and one biological daughter Shiloh, born to the couple.

When Brad Pitt was asked by Italian state TV whether they were ready for a fifth child, he replied: “Yeah we’re ready.”

Brad Pitt told a new conference that he enjoyed being fatherhood. “It’s the most fun I’ve ever had and also the biggest pain … I’ve ever experienced,” he said. “Having four small children makes me much more efficient because when I work, I really have to focus. I know I’ve less time to get things done. Actually, I’m quite pleased by it,” he added.

However, Brad Pitt didn’t say whether the fifth child would be another biological child or adopted one.